Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts.

نویسندگان

  • Masao Tanabiki
  • Kazuhiro Tsuchiya
  • Yukihiro Motoyama
  • Hideo Nagashima
چکیده

The azanickellacyclic complex (1) produced by trimerization of an isocyanide on the nickel atom is found to be a new ethylene polymerization catalyst; catalytic activity is increased by incorporation of the second metal to a diimino moiety of 1 leading to formation of heterobimetallic complexes.

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عنوان ژورنال:
  • Chemical communications

دوره 27  شماره 

صفحات  -

تاریخ انتشار 2005